If you only have part .007, you essentially have a "corrupted" or incomplete document. You cannot extract the data from a single middle segment without the header information usually found in the .001 file .
: Ensure all files (from .001 to the final number) are in the same folder. VPW.7z.007
The "VPW" prefix likely stands for the content of the archive. While "VPW" can refer to many things, common technical associations include: If you only have part